A coordination polymer with conformationally distinct layers: Poly[(μ-1,3-di-4-pyridylpropane-κ2N:N′) bis(μ3-thiocyanato-κ3N,S:S)dicopper(I)]

Ryan J. Trovitch; Randy S. Rarig; Jon A. Zubieta; Robert L. LaDuca

doi:10.1107/S1600536806055395

A coordination polymer with conformationally distinct layers: Poly[(μ-1,3-di-4-pyridylpropane-κ²N:N′) bis(μ₃-thiocyanato-κ³N,S:S)dicopper(I)]

Ryan J. Trovitch
, Randy S. Rarig
, Jon A. Zubieta
, Robert L. LaDuca

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

The title compound, [Cu₂(SCN)₂(C₁₃H ₁₄N₂)]_n, is a two-dimensional coordination polymer containing tetrahedrally coordinated Cu1 atoms bound to one N atom from a 1,3-di-4-pyridylpropane molecule, and one N and two S atoms from three distinct μ₃-thiocyanate anions. The resulting [Cu ₂(SCN)₂] staircase motifs align parallel to the b crystal axis and link through tethering 1,3-di-4-pyridylpropane ligands into layers parallel to the bc crystal plane. Distinct layers with subtly different conformations stack in a BAA′B′ pattern, where the B A and A′B′ double slabs are related by an inversion center.

Original language	English (US)
Pages (from-to)	m339-m341
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	63
Issue number	2
DOIs	https://doi.org/10.1107/S1600536806055395
State	Published - Feb 2007
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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A coordination polymer with conformationally distinct layers: Poly[(μ-1,3-di-4-pyridylpropane-κ²N:N′) bis(μ₃-thiocyanato-κ³N,S:S)dicopper(I)]. / Trovitch, Ryan J.; Rarig, Randy S.; Zubieta, Jon A. et al.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 63, No. 2, 02.2007, p. m339-m341.

Research output: Contribution to journal › Article › peer-review

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title = "A coordination polymer with conformationally distinct layers: Poly[(μ-1,3-di-4-pyridylpropane-κ2N:N′) bis(μ3-thiocyanato-κ3N,S:S)dicopper(I)]",

abstract = "The title compound, [Cu2(SCN)2(C13H 14N2)]n, is a two-dimensional coordination polymer containing tetrahedrally coordinated Cu1 atoms bound to one N atom from a 1,3-di-4-pyridylpropane molecule, and one N and two S atoms from three distinct μ3-thiocyanate anions. The resulting [Cu 2(SCN)2] staircase motifs align parallel to the b crystal axis and link through tethering 1,3-di-4-pyridylpropane ligands into layers parallel to the bc crystal plane. Distinct layers with subtly different conformations stack in a BAA′B′ pattern, where the B A and A′B′ double slabs are related by an inversion center.",

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T2 - Poly[(μ-1,3-di-4-pyridylpropane-κ2N:N′) bis(μ3-thiocyanato-κ3N,S:S)dicopper(I)]

AU - Trovitch, Ryan J.

AU - Rarig, Randy S.

AU - Zubieta, Jon A.

AU - LaDuca, Robert L.

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N2 - The title compound, [Cu2(SCN)2(C13H 14N2)]n, is a two-dimensional coordination polymer containing tetrahedrally coordinated Cu1 atoms bound to one N atom from a 1,3-di-4-pyridylpropane molecule, and one N and two S atoms from three distinct μ3-thiocyanate anions. The resulting [Cu 2(SCN)2] staircase motifs align parallel to the b crystal axis and link through tethering 1,3-di-4-pyridylpropane ligands into layers parallel to the bc crystal plane. Distinct layers with subtly different conformations stack in a BAA′B′ pattern, where the B A and A′B′ double slabs are related by an inversion center.

AB - The title compound, [Cu2(SCN)2(C13H 14N2)]n, is a two-dimensional coordination polymer containing tetrahedrally coordinated Cu1 atoms bound to one N atom from a 1,3-di-4-pyridylpropane molecule, and one N and two S atoms from three distinct μ3-thiocyanate anions. The resulting [Cu 2(SCN)2] staircase motifs align parallel to the b crystal axis and link through tethering 1,3-di-4-pyridylpropane ligands into layers parallel to the bc crystal plane. Distinct layers with subtly different conformations stack in a BAA′B′ pattern, where the B A and A′B′ double slabs are related by an inversion center.

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DO - 10.1107/S1600536806055395

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A coordination polymer with conformationally distinct layers: Poly[(μ-1,3-di-4-pyridylpropane-κ²N:N′) bis(μ₃-thiocyanato-κ³N,S:S)dicopper(I)]

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