A molecular beam optical Stark study of nickel monohydride, NiH

Jinhai Chen; Timothy Steimle

doi:10.1016/j.cplett.2008.03.056

A molecular beam optical Stark study of nickel monohydride, NiH

Jinhai Chen
, Timothy Steimle

Molecular Sciences, School of (SMS)

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The optical Stark effect in the B²Δ_5/2 ← X²Δ_5/2(1-0)Q_e/f(5/2) and P_e/f(7/2) lines of nickel monohydride, ⁵⁸NiH, was recorded and analyzed to produce values for the permanent electric dipole moment, μ, of 2.44 ± 0.02 D and 0.36 ± 0.02 D for the X²Δ_5/2 and B²Δ_5/2 states, respectively. The values are in agreement with the previously determined values [J.A. Gray, S.F. Rice, R.W. Field, J. Chem. Phys. 82 (1985) 4717] and with the experimental error approximately a factor of five smaller. A comparison with theoretical predictions and other first-row transition metal monohydrides is given.

Original language	English (US)
Pages (from-to)	23-25
Number of pages	3
Journal	Chemical Physics Letters
Volume	457
Issue number	1-3
DOIs	https://doi.org/10.1016/j.cplett.2008.03.056
State	Published - May 20 2008

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1016/j.cplett.2008.03.056

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title = "A molecular beam optical Stark study of nickel monohydride, NiH",

abstract = "The optical Stark effect in the B2Δ5/2 ← X2Δ5/2(1-0)Qe/f(5/2) and Pe/f(7/2) lines of nickel monohydride, 58NiH, was recorded and analyzed to produce values for the permanent electric dipole moment, μ, of 2.44 ± 0.02 D and 0.36 ± 0.02 D for the X2Δ5/2 and B2Δ5/2 states, respectively. The values are in agreement with the previously determined values [J.A. Gray, S.F. Rice, R.W. Field, J. Chem. Phys. 82 (1985) 4717] and with the experimental error approximately a factor of five smaller. A comparison with theoretical predictions and other first-row transition metal monohydrides is given.",

author = "Jinhai Chen and Timothy Steimle",

note = "Funding Information: This research has been supported by the National Science Foundation – Experimental Physical Chemistry (Grant No. 0646473). The authors would like to thank Prof. Colan Linton (U. of New Brunswick) for his valuable comments.",

year = "2008",

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doi = "10.1016/j.cplett.2008.03.056",

language = "English (US)",

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pages = "23--25",

journal = "Chemical Physics Letters",

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TY - JOUR

T1 - A molecular beam optical Stark study of nickel monohydride, NiH

AU - Chen, Jinhai

AU - Steimle, Timothy

N1 - Funding Information: This research has been supported by the National Science Foundation – Experimental Physical Chemistry (Grant No. 0646473). The authors would like to thank Prof. Colan Linton (U. of New Brunswick) for his valuable comments.

PY - 2008/5/20

Y1 - 2008/5/20

N2 - The optical Stark effect in the B2Δ5/2 ← X2Δ5/2(1-0)Qe/f(5/2) and Pe/f(7/2) lines of nickel monohydride, 58NiH, was recorded and analyzed to produce values for the permanent electric dipole moment, μ, of 2.44 ± 0.02 D and 0.36 ± 0.02 D for the X2Δ5/2 and B2Δ5/2 states, respectively. The values are in agreement with the previously determined values [J.A. Gray, S.F. Rice, R.W. Field, J. Chem. Phys. 82 (1985) 4717] and with the experimental error approximately a factor of five smaller. A comparison with theoretical predictions and other first-row transition metal monohydrides is given.

AB - The optical Stark effect in the B2Δ5/2 ← X2Δ5/2(1-0)Qe/f(5/2) and Pe/f(7/2) lines of nickel monohydride, 58NiH, was recorded and analyzed to produce values for the permanent electric dipole moment, μ, of 2.44 ± 0.02 D and 0.36 ± 0.02 D for the X2Δ5/2 and B2Δ5/2 states, respectively. The values are in agreement with the previously determined values [J.A. Gray, S.F. Rice, R.W. Field, J. Chem. Phys. 82 (1985) 4717] and with the experimental error approximately a factor of five smaller. A comparison with theoretical predictions and other first-row transition metal monohydrides is given.

UR - https://www.scopus.com/pages/publications/43549085006

UR - https://www.scopus.com/pages/publications/43549085006#tab=citedBy

U2 - 10.1016/j.cplett.2008.03.056

DO - 10.1016/j.cplett.2008.03.056

M3 - Article

SN - 0009-2614

VL - 457

SP - 23

EP - 25

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1-3

ER -

A molecular beam optical Stark study of nickel monohydride, NiH

Abstract

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