An aryl diimine cobalt(i) catalyst for carbonyl hydrosilylation

Anuja Sharma; Sangho So; Jun Hyeong Kim; Samantha N. MacMillan; Mu Hyun Baik; Ryan J. Trovitch

doi:10.1039/d2cc04089a

An aryl diimine cobalt(i) catalyst for carbonyl hydrosilylation

Anuja Sharma
, Sangho So
, Jun Hyeong Kim
, Samantha N. MacMillan
, Mu Hyun Baik
, Ryan J. Trovitch

Molecular Sciences, School of (SMS)

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Through the application of a redox-innocent aryl diimine chelate, the discovery and utilization of a cobalt catalyst, (^Ph₂PPrADI)Co, that exhibits carbonyl hydrosilylation turnover frequencies of up to 330 s⁻¹ is described. This activity is believed to be the highest ever reported for metal-catalyzed carbonyl hydrosilylation.

Original language	English (US)
Pages (from-to)	10793-10796
Number of pages	4
Journal	Chemical Communications
Volume	58
Issue number	77
DOIs	https://doi.org/10.1039/d2cc04089a
State	Published - Aug 24 2022

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
General Chemistry
Catalysis

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10.1039/d2cc04089a

Cite this

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abstract = "Through the application of a redox-innocent aryl diimine chelate, the discovery and utilization of a cobalt catalyst, (Ph2PPrADI)Co, that exhibits carbonyl hydrosilylation turnover frequencies of up to 330 s−1 is described. This activity is believed to be the highest ever reported for metal-catalyzed carbonyl hydrosilylation.",

author = "Anuja Sharma and Sangho So and Kim, \{Jun Hyeong\} and MacMillan, \{Samantha N.\} and Baik, \{Mu Hyun\} and Trovitch, \{Ryan J.\}",

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AU - Sharma, Anuja

AU - So, Sangho

AU - Kim, Jun Hyeong

AU - MacMillan, Samantha N.

AU - Baik, Mu Hyun

AU - Trovitch, Ryan J.

PY - 2022/8/24

Y1 - 2022/8/24

N2 - Through the application of a redox-innocent aryl diimine chelate, the discovery and utilization of a cobalt catalyst, (Ph2PPrADI)Co, that exhibits carbonyl hydrosilylation turnover frequencies of up to 330 s−1 is described. This activity is believed to be the highest ever reported for metal-catalyzed carbonyl hydrosilylation.

AB - Through the application of a redox-innocent aryl diimine chelate, the discovery and utilization of a cobalt catalyst, (Ph2PPrADI)Co, that exhibits carbonyl hydrosilylation turnover frequencies of up to 330 s−1 is described. This activity is believed to be the highest ever reported for metal-catalyzed carbonyl hydrosilylation.

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DO - 10.1039/d2cc04089a

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JO - Chemical Communications

JF - Chemical Communications

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ER -

An aryl diimine cobalt(i) catalyst for carbonyl hydrosilylation

Abstract

ASJC Scopus subject areas

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