Arylene- and Alkylene-Bridged Siliconates

Douglas A. Loy; James H. Small; Kenneth J. Shea

doi:10.1021/om00028a083

Arylene- and Alkylene-Bridged Siliconates

Douglas A. Loy
, James H. Small
, Kenneth J. Shea

Research output: Contribution to journal › Comment/debate › peer-review

17 Scopus citations

Abstract

Arylene-bridged pentacoordinate siliconates 3-6 (arylene = 1,4-phenylene, 1,3-phenylene, 4,4′-biphenylene, and 9,10-anthracylene) were prepared from bis(triethoxysilyl)arylene precursors, catechol, and tri-ethylamine in tetrahydrofuran. 1,2-Ethylene and 1,6-hexylene-bridged pentacoordinate siliconates 7 and 8 were prepared from 1,2-bis(trimethoxysilyl)ethane and 1,6-bis(trimethoxysilyl)hexane, respectively. The molecular structure of the 1,4-phenylene-bridged siliconate 3 was determined by X-ray diffraction.

Original language	English (US)
Pages (from-to)	1484-1488
Number of pages	5
Journal	Organometallics
Volume	12
Issue number	4
DOIs	https://doi.org/10.1021/om00028a083
State	Published - 1993
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "Arylene- and Alkylene-Bridged Siliconates",

abstract = "Arylene-bridged pentacoordinate siliconates 3-6 (arylene = 1,4-phenylene, 1,3-phenylene, 4,4′-biphenylene, and 9,10-anthracylene) were prepared from bis(triethoxysilyl)arylene precursors, catechol, and tri-ethylamine in tetrahydrofuran. 1,2-Ethylene and 1,6-hexylene-bridged pentacoordinate siliconates 7 and 8 were prepared from 1,2-bis(trimethoxysilyl)ethane and 1,6-bis(trimethoxysilyl)hexane, respectively. The molecular structure of the 1,4-phenylene-bridged siliconate 3 was determined by X-ray diffraction.",

author = "Loy, \{Douglas A.\} and Small, \{James H.\} and Shea, \{Kenneth J.\}",

year = "1993",

doi = "10.1021/om00028a083",

language = "English (US)",

volume = "12",

pages = "1484--1488",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "4",

}

TY - JOUR

T1 - Arylene- and Alkylene-Bridged Siliconates

AU - Loy, Douglas A.

AU - Small, James H.

AU - Shea, Kenneth J.

PY - 1993

Y1 - 1993

N2 - Arylene-bridged pentacoordinate siliconates 3-6 (arylene = 1,4-phenylene, 1,3-phenylene, 4,4′-biphenylene, and 9,10-anthracylene) were prepared from bis(triethoxysilyl)arylene precursors, catechol, and tri-ethylamine in tetrahydrofuran. 1,2-Ethylene and 1,6-hexylene-bridged pentacoordinate siliconates 7 and 8 were prepared from 1,2-bis(trimethoxysilyl)ethane and 1,6-bis(trimethoxysilyl)hexane, respectively. The molecular structure of the 1,4-phenylene-bridged siliconate 3 was determined by X-ray diffraction.

AB - Arylene-bridged pentacoordinate siliconates 3-6 (arylene = 1,4-phenylene, 1,3-phenylene, 4,4′-biphenylene, and 9,10-anthracylene) were prepared from bis(triethoxysilyl)arylene precursors, catechol, and tri-ethylamine in tetrahydrofuran. 1,2-Ethylene and 1,6-hexylene-bridged pentacoordinate siliconates 7 and 8 were prepared from 1,2-bis(trimethoxysilyl)ethane and 1,6-bis(trimethoxysilyl)hexane, respectively. The molecular structure of the 1,4-phenylene-bridged siliconate 3 was determined by X-ray diffraction.

UR - https://www.scopus.com/pages/publications/0043250975

UR - https://www.scopus.com/pages/publications/0043250975#tab=citedBy

U2 - 10.1021/om00028a083

DO - 10.1021/om00028a083

M3 - Comment/debate

SN - 0276-7333

VL - 12

SP - 1484

EP - 1488

JO - Organometallics

JF - Organometallics

IS - 4

ER -

Arylene- and Alkylene-Bridged Siliconates

Abstract

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