Carbene and Silicon Routes toward a Simple Nitrile Ylide. Spectroscopic, Kinetic, and Chemical Characterization

Nicholas J. Turro; Yuan Cha; Ian R. Gould; Albert Padwa; John R. Gasdaska; Miguel Tomas

doi:10.1021/jo00222a053

Carbene and Silicon Routes toward a Simple Nitrile Ylide. Spectroscopic, Kinetic, and Chemical Characterization

Nicholas J. Turro
, Yuan Cha
, Ian R. Gould
, Albert Padwa
, John R. Gasdaska
, Miguel Tomas

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

The generation and characterization of methyl nitrile ylide photochemically by addition of singlet methylene to acetonitrile and chemically from a silylthioimidate and subsequent dipolar cycloaddition are carried out.

Original language	English (US)
Pages (from-to)	4415-4417
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	50
Issue number	22
DOIs	https://doi.org/10.1021/jo00222a053
State	Published - Nov 1985
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry

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10.1021/jo00222a053

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@article{257a066b1f67411cba5a2366a8bcf534,

title = "Carbene and Silicon Routes toward a Simple Nitrile Ylide. Spectroscopic, Kinetic, and Chemical Characterization",

abstract = "The generation and characterization of methyl nitrile ylide photochemically by addition of singlet methylene to acetonitrile and chemically from a silylthioimidate and subsequent dipolar cycloaddition are carried out.",

author = "Turro, \{Nicholas J.\} and Yuan Cha and Gould, \{Ian R.\} and Albert Padwa and Gasdaska, \{John R.\} and Miguel Tomas",

year = "1985",

month = nov,

doi = "10.1021/jo00222a053",

language = "English (US)",

volume = "50",

pages = "4415--4417",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "22",

}

TY - JOUR

T1 - Carbene and Silicon Routes toward a Simple Nitrile Ylide. Spectroscopic, Kinetic, and Chemical Characterization

AU - Turro, Nicholas J.

AU - Cha, Yuan

AU - Gould, Ian R.

AU - Padwa, Albert

AU - Gasdaska, John R.

AU - Tomas, Miguel

PY - 1985/11

Y1 - 1985/11

N2 - The generation and characterization of methyl nitrile ylide photochemically by addition of singlet methylene to acetonitrile and chemically from a silylthioimidate and subsequent dipolar cycloaddition are carried out.

AB - The generation and characterization of methyl nitrile ylide photochemically by addition of singlet methylene to acetonitrile and chemically from a silylthioimidate and subsequent dipolar cycloaddition are carried out.

UR - https://www.scopus.com/pages/publications/0001697851

UR - https://www.scopus.com/pages/publications/0001697851#tab=citedBy

U2 - 10.1021/jo00222a053

DO - 10.1021/jo00222a053

M3 - Article

SN - 0022-3263

VL - 50

SP - 4415

EP - 4417

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 22

ER -

Carbene and Silicon Routes toward a Simple Nitrile Ylide. Spectroscopic, Kinetic, and Chemical Characterization

Abstract

ASJC Scopus subject areas

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