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Effect of Nb Alloying Addition on Local Phase Transformation at Microtwin Boundaries in Nickel-Based Superalloys

  • A. J. Egan
  • , Y. Rao
  • , G. B. Viswanathan
  • , T. M. Smith
  • , M. Ghazisaeidi
  • , S. Tin
  • , M. J. Mills

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

This work investigates two nominally similar polycrystalline alloys, with a subtle difference in Nb content, intended to elucidate its effect on local phase transformation strengthening during high temperature creep. Tests were conducted at 750 °C and 600 MPa to target the creep regime dominated by superlattice intrinsic and extrinsic stacking faults, as well as microtwinning. Alloy A, with higher Nb and lower Al, was found to be superior in creep strength to Alloy B, with lower Nb and higher Al, as well as previously investigated ME3 and LSHR. Atomic resolution scanning transmission electron microscopy and energy-dispersive spectroscopy found that this increased creep strength was due to a novel local phase transformation occurring along microtwin boundary interfaces as a result of the Nb increase. Complementary density functional theory calculations helped to confirm that this was χ phase formation. It is hypothesized that this transformation was the cause of the increased creep strength exhibited by Alloy A.

Original languageEnglish (US)
Title of host publicationSuperalloys 2020 - Proceedings of the 14th International Symposium on Superalloys
EditorsSammy Tin, Mark Hardy, Justin Clews, Jonathan Cormier, Qiang Feng, John Marcin, Chris O'Brien, Akane Suzuki
PublisherSpringer Science and Business Media Deutschland GmbH
Pages640-650
Number of pages11
ISBN (Print)9783030518332
DOIs
StatePublished - 2020
Externally publishedYes
Event14th International Symposium on Superalloys, Superalloys 2021 - Seven Springs, United States
Duration: Sep 12 2021 → Sep 16 2021

Publication series

NameMinerals, Metals and Materials Series

Conference

Conference14th International Symposium on Superalloys, Superalloys 2021
Country/TerritoryUnited States
CitySeven Springs
Period9/12/21 → 9/16/21

Keywords

  • Creep
  • HAADF
  • Local phase transformation
  • Microtwin
  • STEM

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Energy Engineering and Power Technology
  • Mechanics of Materials
  • Metals and Alloys
  • Materials Chemistry

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