Electrochemical electrophilic aromatic methylthiation in liquid SO2

Richard S. Glass; Viatcheslav V. Jouikov

doi:10.1016/S0040-4039(99)01311-8

Electrochemical electrophilic aromatic methylthiation in liquid SO₂

Richard S. Glass, Viatcheslav V. Jouikov

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

Controlled potential electrolysis of dimethyldisulfide in liquid sulfur dioxide provides a strongly electrophilic methylthiating agent. This species methylthiates strongly to weakly activated arenes in good to excellent yield.

Original language	English (US)
Pages (from-to)	6357-6358
Number of pages	2
Journal	Tetrahedron Letters
Volume	40
Issue number	35
DOIs	https://doi.org/10.1016/S0040-4039(99)01311-8
State	Published - Aug 27 1999

Keywords

Disulfide
Electrochemistry
Electrophilic aromatic substitution
Sulfur dioxide

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

Access to Document

10.1016/S0040-4039(99)01311-8

Cite this

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title = "Electrochemical electrophilic aromatic methylthiation in liquid SO2",

abstract = "Controlled potential electrolysis of dimethyldisulfide in liquid sulfur dioxide provides a strongly electrophilic methylthiating agent. This species methylthiates strongly to weakly activated arenes in good to excellent yield.",

keywords = "Disulfide, Electrochemistry, Electrophilic aromatic substitution, Sulfur dioxide",

author = "Glass, {Richard S.} and Jouikov, {Viatcheslav V.}",

year = "1999",

month = aug,

day = "27",

doi = "10.1016/S0040-4039(99)01311-8",

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pages = "6357--6358",

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T1 - Electrochemical electrophilic aromatic methylthiation in liquid SO2

AU - Glass, Richard S.

AU - Jouikov, Viatcheslav V.

PY - 1999/8/27

Y1 - 1999/8/27

N2 - Controlled potential electrolysis of dimethyldisulfide in liquid sulfur dioxide provides a strongly electrophilic methylthiating agent. This species methylthiates strongly to weakly activated arenes in good to excellent yield.

AB - Controlled potential electrolysis of dimethyldisulfide in liquid sulfur dioxide provides a strongly electrophilic methylthiating agent. This species methylthiates strongly to weakly activated arenes in good to excellent yield.

KW - Disulfide

KW - Electrochemistry

KW - Electrophilic aromatic substitution

KW - Sulfur dioxide

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U2 - 10.1016/S0040-4039(99)01311-8

DO - 10.1016/S0040-4039(99)01311-8

M3 - Article

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SP - 6357

EP - 6358

JO - Tetrahedron Letters

JF - Tetrahedron Letters

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