TY - JOUR
T1 - Infrared and Raman spectra and vibrational assignments for 4-(dimethylamino)benzaldehyde and its zinc complex
AU - Rosencrance, James G.
AU - Jagodzinski, Paul W.
PY - 1986
Y1 - 1986
N2 - The vibrational spectra of 4-(dimethylamino)benzaldehyde (DABA) and its zinc complex are presented and vibrational assignments are proposed. Significant differences between the spectra of the parent molecule and the complex are observed. Examination of the form of the normal modes facilitates explanation of proposed frequency shifts of ring modes upon complexation. The spectra of the complex are interpreted by employing a quinonoid-type structure for the DABA ligand.
AB - The vibrational spectra of 4-(dimethylamino)benzaldehyde (DABA) and its zinc complex are presented and vibrational assignments are proposed. Significant differences between the spectra of the parent molecule and the complex are observed. Examination of the form of the normal modes facilitates explanation of proposed frequency shifts of ring modes upon complexation. The spectra of the complex are interpreted by employing a quinonoid-type structure for the DABA ligand.
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U2 - 10.1016/0584-8539(86)80205-7
DO - 10.1016/0584-8539(86)80205-7
M3 - Article
SN - 0584-8539
VL - 42
SP - 869
EP - 879
JO - Spectrochimica Acta - Part A Molecular Spectroscopy
JF - Spectrochimica Acta - Part A Molecular Spectroscopy
IS - 8
ER -