Layer rigidity in 2D disordered NiAl layer double hydroxides

S. A. Solin; D. Hines; S. K. Yun; T. J. Pinnavaia

doi:10.1016/0022-3093(94)00541-9

Layer rigidity in 2D disordered NiAl layer double hydroxides

S. A. Solin
, D. Hines
, S. K. Yun
, T. J. Pinnavaia

Arizona State University

Research output: Contribution to journal › Article › peer-review

49 Scopus citations

Abstract

A series of layer double hydroxide carbonates with the chemical composition [(CO₃)_{x 2} · y(H₂O)][Ni_{1 - x}Al_x(OH)₂], 0 < x < 0.4, 0 < y < 1.2 has been prepared. The composition dependence of the basal spacing of these compounds has been determined from X-ray diffraction measurements and has been computed using an extended version of the discrete finite-layer rigidity model which includes both intra- and inter-layer rigidity effects. The inter- and intra-layer rigidity parameters of Ni(OH)₂ were found to be ∼ 5 and 2.44, respectively, from which we conclude that the host Ni(OH)₂ spans class II and class III layered solids. On the basis of our X-ray measurements and steric considerations, it is determined that the carbonate ion is oriented in the host gallery with its threefold axis essentially parallel to the host c-axis.

Original language	English (US)
Pages (from-to)	212-220
Number of pages	9
Journal	Journal of Non-Crystalline Solids
Volume	182
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-3093(94)00541-9
State	Published - Mar 1 1995

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Materials Chemistry

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10.1016/0022-3093(94)00541-9

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@article{e4c002416d414ab0b62e9dd84bb32bee,

title = "Layer rigidity in 2D disordered NiAl layer double hydroxides",

abstract = "A series of layer double hydroxide carbonates with the chemical composition [(CO3) x 2 · y(H2O)][Ni1 - xAlx(OH)2], 0 < x < 0.4, 0 < y < 1.2 has been prepared. The composition dependence of the basal spacing of these compounds has been determined from X-ray diffraction measurements and has been computed using an extended version of the discrete finite-layer rigidity model which includes both intra- and inter-layer rigidity effects. The inter- and intra-layer rigidity parameters of Ni(OH)2 were found to be ∼ 5 and 2.44, respectively, from which we conclude that the host Ni(OH)2 spans class II and class III layered solids. On the basis of our X-ray measurements and steric considerations, it is determined that the carbonate ion is oriented in the host gallery with its threefold axis essentially parallel to the host c-axis.",

author = "Solin, \{S. A.\} and D. Hines and Yun, \{S. K.\} and Pinnavaia, \{T. J.\}",

note = "Funding Information: The authors gratefully acknowledge useful discussions with J. Chadi, S. Dhingra, R. Haushalter and G. Seidler. The MSU portion of this work was supported by the NSF under the Chemical Research Group (CRG) grant CHE-92 24102 and in-part by the MSU Center for Fundamental Materials Research.",

year = "1995",

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doi = "10.1016/0022-3093(94)00541-9",

language = "English (US)",

volume = "182",

pages = "212--220",

journal = "Journal of Non-Crystalline Solids",

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T1 - Layer rigidity in 2D disordered NiAl layer double hydroxides

AU - Solin, S. A.

AU - Hines, D.

AU - Yun, S. K.

AU - Pinnavaia, T. J.

N1 - Funding Information: The authors gratefully acknowledge useful discussions with J. Chadi, S. Dhingra, R. Haushalter and G. Seidler. The MSU portion of this work was supported by the NSF under the Chemical Research Group (CRG) grant CHE-92 24102 and in-part by the MSU Center for Fundamental Materials Research.

PY - 1995/3/1

Y1 - 1995/3/1

N2 - A series of layer double hydroxide carbonates with the chemical composition [(CO3) x 2 · y(H2O)][Ni1 - xAlx(OH)2], 0 < x < 0.4, 0 < y < 1.2 has been prepared. The composition dependence of the basal spacing of these compounds has been determined from X-ray diffraction measurements and has been computed using an extended version of the discrete finite-layer rigidity model which includes both intra- and inter-layer rigidity effects. The inter- and intra-layer rigidity parameters of Ni(OH)2 were found to be ∼ 5 and 2.44, respectively, from which we conclude that the host Ni(OH)2 spans class II and class III layered solids. On the basis of our X-ray measurements and steric considerations, it is determined that the carbonate ion is oriented in the host gallery with its threefold axis essentially parallel to the host c-axis.

AB - A series of layer double hydroxide carbonates with the chemical composition [(CO3) x 2 · y(H2O)][Ni1 - xAlx(OH)2], 0 < x < 0.4, 0 < y < 1.2 has been prepared. The composition dependence of the basal spacing of these compounds has been determined from X-ray diffraction measurements and has been computed using an extended version of the discrete finite-layer rigidity model which includes both intra- and inter-layer rigidity effects. The inter- and intra-layer rigidity parameters of Ni(OH)2 were found to be ∼ 5 and 2.44, respectively, from which we conclude that the host Ni(OH)2 spans class II and class III layered solids. On the basis of our X-ray measurements and steric considerations, it is determined that the carbonate ion is oriented in the host gallery with its threefold axis essentially parallel to the host c-axis.

UR - https://www.scopus.com/pages/publications/0003007671

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U2 - 10.1016/0022-3093(94)00541-9

DO - 10.1016/0022-3093(94)00541-9

M3 - Article

SN - 0022-3093

VL - 182

SP - 212

EP - 220

JO - Journal of Non-Crystalline Solids

JF - Journal of Non-Crystalline Solids

IS - 1-2

ER -

Layer rigidity in 2D disordered NiAl layer double hydroxides

Abstract

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