Mechanism of the Base-Induced Decomposition of iV-Nitroso-iV-methylurea

Sidney M. Hecht; John W. Kozarich

doi:10.1021/jo00950a011

Mechanism of the Base-Induced Decomposition of iV-Nitroso-iV-methylurea

Sidney M. Hecht
, John W. Kozarich

Research output: Contribution to journal › Article › peer-review

39 Scopus citations

Abstract

The mechanism corresponding to the base-induced decomposition of N-nitroso-N-methylurea is discussed. Evidence is presented for the decomposition which is consistent with initial abstraction of a urea proton, but not with a mechanism involving initial nucleophilic addition to the nitroso or carbonyl groups.

Original language	English (US)
Pages (from-to)	1821-1824
Number of pages	4
Journal	Journal of Organic Chemistry
Volume	38
Issue number	10
DOIs	https://doi.org/10.1021/jo00950a011
State	Published - May 1 1973
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry

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@article{71e4dc47408d4a6c868a98d2d6902cf6,

title = "Mechanism of the Base-Induced Decomposition of iV-Nitroso-iV-methylurea",

abstract = "The mechanism corresponding to the base-induced decomposition of N-nitroso-N-methylurea is discussed. Evidence is presented for the decomposition which is consistent with initial abstraction of a urea proton, but not with a mechanism involving initial nucleophilic addition to the nitroso or carbonyl groups.",

author = "Hecht, \{Sidney M.\} and Kozarich, \{John W.\}",

year = "1973",

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language = "English (US)",

volume = "38",

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journal = "Journal of Organic Chemistry",

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publisher = "American Chemical Society",

number = "10",

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T1 - Mechanism of the Base-Induced Decomposition of iV-Nitroso-iV-methylurea

AU - Hecht, Sidney M.

AU - Kozarich, John W.

PY - 1973/5/1

Y1 - 1973/5/1

N2 - The mechanism corresponding to the base-induced decomposition of N-nitroso-N-methylurea is discussed. Evidence is presented for the decomposition which is consistent with initial abstraction of a urea proton, but not with a mechanism involving initial nucleophilic addition to the nitroso or carbonyl groups.

AB - The mechanism corresponding to the base-induced decomposition of N-nitroso-N-methylurea is discussed. Evidence is presented for the decomposition which is consistent with initial abstraction of a urea proton, but not with a mechanism involving initial nucleophilic addition to the nitroso or carbonyl groups.

UR - https://www.scopus.com/pages/publications/0011490204

UR - https://www.scopus.com/pages/publications/0011490204#tab=citedBy

U2 - 10.1021/jo00950a011

DO - 10.1021/jo00950a011

M3 - Article

SN - 0022-3263

VL - 38

SP - 1821

EP - 1824

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 10

ER -

Mechanism of the Base-Induced Decomposition of iV-Nitroso-iV-methylurea

Abstract

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