@article{48f7b0a612a44231a4fa94ca9cb9ffea,
title = "Molecular-Modified Photocathodes for Applications in Artificial Photosynthesis and Solar-to-Fuel Technologies",
abstract = "Nature offers inspiration for developing technologies that integrate the capture, conversion, and storage of solar energy. In this review article, we highlight principles of natural photosynthesis and artificial photosynthesis, drawing comparisons between solar energy transduction in biology and emerging solar-to-fuel technologies. Key features of the biological approach include use of earth-abundant elements and molecular interfaces for driving photoinduced charge separation reactions that power chemical transformations at global scales. For the artificial systems described in this review, emphasis is placed on advancements involving hybrid photocathodes that power fuel-forming reactions using molecular catalysts interfaced with visible-light-absorbing semiconductors.",
author = "{Reyes Cruz}, {Edgar A.} and Daiki Nishiori and Wadsworth, {Brian L.} and Nguyen, {Nghi P.} and Hensleigh, {Lillian K.} and Diana Khusnutdinova and Beiler, {Anna M.} and Moore, {G. F.}",
note = "Funding Information: This material is based upon work supported by the National Science Foundation under Early Career Award 1653982 (materials and synthesis) and by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Early Career Award DE-SC0021186 (modeling and benchmarking). G.F.M. acknowledges support from the Camille Dreyfus Teacher-Scholar Awards Program. B.L.W. and A.M.B. were supported by IGERT-SUN fellowships, funded by the National Science Foundation (1144616), and the Phoenix Chapter of the ARCS Foundation. D.N. was supported by the Heiwa Nakajima Foundation. Publisher Copyright: {\textcopyright} 2022 American Chemical Society. All rights reserved.",
year = "2022",
month = nov,
day = "9",
doi = "10.1021/acs.chemrev.2c00200",
language = "English (US)",
volume = "122",
pages = "16051--16109",
journal = "Chemical reviews",
issn = "0009-2665",
publisher = "American Chemical Society",
number = "21",
}