Neutral and charged soliton defects in polyacetylene

R. R. Chance; D. S. Boudreaux; J. L. Brédas; R. Silbey

doi:10.1103/PhysRevB.27.1440

Neutral and charged soliton defects in polyacetylene

R. R. Chance
, D. S. Boudreaux
, J. L. Brédas
, R. Silbey

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

Self-consistent-field calculations have been applied to the study of defect geometries in finite-chain models of polyacetylene. The extent of the disruption of the normal bond-length pattern is less than previously expected and varies with the charge state. It is shown that the charged (neutral) defects induce a spatially damped, charge- (spin-) density wave of extent greater than that of the lattice kink itself.

Original language	English (US)
Pages (from-to)	1440-1442
Number of pages	3
Journal	Physical Review B
Volume	27
Issue number	2
DOIs	https://doi.org/10.1103/PhysRevB.27.1440
State	Published - 1983
Externally published	Yes

ASJC Scopus subject areas

Condensed Matter Physics

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10.1103/PhysRevB.27.1440

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title = "Neutral and charged soliton defects in polyacetylene",

abstract = "Self-consistent-field calculations have been applied to the study of defect geometries in finite-chain models of polyacetylene. The extent of the disruption of the normal bond-length pattern is less than previously expected and varies with the charge state. It is shown that the charged (neutral) defects induce a spatially damped, charge- (spin-) density wave of extent greater than that of the lattice kink itself.",

author = "Chance, \{R. R.\} and Boudreaux, \{D. S.\} and Br{\'e}das, \{J. L.\} and R. Silbey",

year = "1983",

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AU - Chance, R. R.

AU - Boudreaux, D. S.

AU - Brédas, J. L.

AU - Silbey, R.

PY - 1983

Y1 - 1983

N2 - Self-consistent-field calculations have been applied to the study of defect geometries in finite-chain models of polyacetylene. The extent of the disruption of the normal bond-length pattern is less than previously expected and varies with the charge state. It is shown that the charged (neutral) defects induce a spatially damped, charge- (spin-) density wave of extent greater than that of the lattice kink itself.

AB - Self-consistent-field calculations have been applied to the study of defect geometries in finite-chain models of polyacetylene. The extent of the disruption of the normal bond-length pattern is less than previously expected and varies with the charge state. It is shown that the charged (neutral) defects induce a spatially damped, charge- (spin-) density wave of extent greater than that of the lattice kink itself.

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UR - https://www.scopus.com/pages/publications/5844399171#tab=citedBy

U2 - 10.1103/PhysRevB.27.1440

DO - 10.1103/PhysRevB.27.1440

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JO - Physical Review B

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IS - 2

ER -

Neutral and charged soliton defects in polyacetylene

Abstract

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