Selective oxidation of n-butane to maleic anhydride by model VPO catalysts

T. P. Moser; G. L. Schrader

doi:10.1016/0021-9517(85)90256-8

Selective oxidation of n-butane to maleic anhydride by model VPO catalysts

T. P. Moser, G. L. Schrader

Research output: Contribution to journal › Article › peer-review

82 Scopus citations

Abstract

The selective oxidation of n-butane to maleic anhydride was studied using two model vanadium-phosphorus-oxygen catalysts, β-VOPO₄ and (VO)₂P₂O₇. Detailed information concerning the synthesis and characterization of these phases was developed, which indicated the sensitivity of the syntheses to preparation procedures. New information regarding the possible reaction pathway was provided by the detection of 1-butene, 2-butenes, and 1,3-butadiene simultaneously with the production of maleic anhydride. The stability of the pure phases under reaction conditions was examined using in situ laser Raman spectroscopy.

Original language	English (US)
Pages (from-to)	216-231
Number of pages	16
Journal	Journal of Catalysis
Volume	92
Issue number	2
DOIs	https://doi.org/10.1016/0021-9517(85)90256-8
State	Published - Apr 1985
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Physical and Theoretical Chemistry

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10.1016/0021-9517(85)90256-8

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title = "Selective oxidation of n-butane to maleic anhydride by model VPO catalysts",

abstract = "The selective oxidation of n-butane to maleic anhydride was studied using two model vanadium-phosphorus-oxygen catalysts, β-VOPO4 and (VO)2P2O7. Detailed information concerning the synthesis and characterization of these phases was developed, which indicated the sensitivity of the syntheses to preparation procedures. New information regarding the possible reaction pathway was provided by the detection of 1-butene, 2-butenes, and 1,3-butadiene simultaneously with the production of maleic anhydride. The stability of the pure phases under reaction conditions was examined using in situ laser Raman spectroscopy.",

author = "Moser, {T. P.} and Schrader, {G. L.}",

note = "Funding Information: This work was conductedt hrought he Ames Laboratory which is operatedf or the U.S. Departmento f Energy by Iowa State University under Contract W-7405-Eng-82T. his research was supportedb y the Office of Basic Energy Sciences, Chemical Sciences Division. The scanninge lectron microscopy work done by David Bohlen is gratefully acknowledged.",

year = "1985",

month = apr,

doi = "10.1016/0021-9517(85)90256-8",

language = "English (US)",

volume = "92",

pages = "216--231",

journal = "Journal of Catalysis",

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publisher = "Academic Press Inc.",

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TY - JOUR

T1 - Selective oxidation of n-butane to maleic anhydride by model VPO catalysts

AU - Moser, T. P.

AU - Schrader, G. L.

N1 - Funding Information: This work was conductedt hrought he Ames Laboratory which is operatedf or the U.S. Departmento f Energy by Iowa State University under Contract W-7405-Eng-82T. his research was supportedb y the Office of Basic Energy Sciences, Chemical Sciences Division. The scanninge lectron microscopy work done by David Bohlen is gratefully acknowledged.

PY - 1985/4

Y1 - 1985/4

N2 - The selective oxidation of n-butane to maleic anhydride was studied using two model vanadium-phosphorus-oxygen catalysts, β-VOPO4 and (VO)2P2O7. Detailed information concerning the synthesis and characterization of these phases was developed, which indicated the sensitivity of the syntheses to preparation procedures. New information regarding the possible reaction pathway was provided by the detection of 1-butene, 2-butenes, and 1,3-butadiene simultaneously with the production of maleic anhydride. The stability of the pure phases under reaction conditions was examined using in situ laser Raman spectroscopy.

AB - The selective oxidation of n-butane to maleic anhydride was studied using two model vanadium-phosphorus-oxygen catalysts, β-VOPO4 and (VO)2P2O7. Detailed information concerning the synthesis and characterization of these phases was developed, which indicated the sensitivity of the syntheses to preparation procedures. New information regarding the possible reaction pathway was provided by the detection of 1-butene, 2-butenes, and 1,3-butadiene simultaneously with the production of maleic anhydride. The stability of the pure phases under reaction conditions was examined using in situ laser Raman spectroscopy.

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JO - Journal of Catalysis

JF - Journal of Catalysis

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ER -

Selective oxidation of n-butane to maleic anhydride by model VPO catalysts

Abstract

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