The permanent electric dipole moment of nickel oxide, NiO

Damian L. Kokkin; David Dewberry; Timothy Steimle

doi:10.1016/j.cplett.2014.06.027

The permanent electric dipole moment of nickel oxide, NiO

Damian L. Kokkin
, David Dewberry
, Timothy Steimle

Molecular Sciences, School of (SMS)

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

The optical Stark effect in numerous low-J branch features in the Ω=0⁺ ← X³Σ₀^- band near 19 040 cm^-1 of nickel oxide, NiO, has been recorded and analyzed. The permanent electric dipole moment, μ→_el, for the X³Σ₀^-(v=0) and [19.04] Ω=0⁺ states were determined to be 4.43 ± 0.04 D and 1.85 ± 0.16 D, respectively. The measured dipole moments of NiO are compared to those from theoretical predictions and the trend across the 3d-metal monoxide series discussed. The field-free spectrum was analyzed to produce an improved set of fine structure parameters for the [19.04] Ω=0⁺ state.

Original language	English (US)
Pages (from-to)	1-5
Number of pages	5
Journal	Chemical Physics Letters
Volume	609
DOIs	https://doi.org/10.1016/j.cplett.2014.06.027
State	Published - Aug 5 2014

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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title = "The permanent electric dipole moment of nickel oxide, NiO",

abstract = "The optical Stark effect in numerous low-J branch features in the Ω=0+ ← X3Σ0- band near 19 040 cm-1 of nickel oxide, NiO, has been recorded and analyzed. The permanent electric dipole moment, μ→el, for the X3Σ0-(v=0) and [19.04] Ω=0+ states were determined to be 4.43 ± 0.04 D and 1.85 ± 0.16 D, respectively. The measured dipole moments of NiO are compared to those from theoretical predictions and the trend across the 3d-metal monoxide series discussed. The field-free spectrum was analyzed to produce an improved set of fine structure parameters for the [19.04] Ω=0+ state.",

author = "Kokkin, \{Damian L.\} and David Dewberry and Timothy Steimle",

note = "Funding Information: This research at Arizona State University has been supported by a Grant from the National Science Foundation, Division of Chemistry , CHE-1265885 . The authors thank Prof. Colin Linton (University of New Brunswick) for his comments.",

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doi = "10.1016/j.cplett.2014.06.027",

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T1 - The permanent electric dipole moment of nickel oxide, NiO

AU - Kokkin, Damian L.

AU - Dewberry, David

AU - Steimle, Timothy

N1 - Funding Information: This research at Arizona State University has been supported by a Grant from the National Science Foundation, Division of Chemistry , CHE-1265885 . The authors thank Prof. Colin Linton (University of New Brunswick) for his comments.

PY - 2014/8/5

Y1 - 2014/8/5

N2 - The optical Stark effect in numerous low-J branch features in the Ω=0+ ← X3Σ0- band near 19 040 cm-1 of nickel oxide, NiO, has been recorded and analyzed. The permanent electric dipole moment, μ→el, for the X3Σ0-(v=0) and [19.04] Ω=0+ states were determined to be 4.43 ± 0.04 D and 1.85 ± 0.16 D, respectively. The measured dipole moments of NiO are compared to those from theoretical predictions and the trend across the 3d-metal monoxide series discussed. The field-free spectrum was analyzed to produce an improved set of fine structure parameters for the [19.04] Ω=0+ state.

AB - The optical Stark effect in numerous low-J branch features in the Ω=0+ ← X3Σ0- band near 19 040 cm-1 of nickel oxide, NiO, has been recorded and analyzed. The permanent electric dipole moment, μ→el, for the X3Σ0-(v=0) and [19.04] Ω=0+ states were determined to be 4.43 ± 0.04 D and 1.85 ± 0.16 D, respectively. The measured dipole moments of NiO are compared to those from theoretical predictions and the trend across the 3d-metal monoxide series discussed. The field-free spectrum was analyzed to produce an improved set of fine structure parameters for the [19.04] Ω=0+ state.

UR - https://www.scopus.com/pages/publications/84903616753

UR - https://www.scopus.com/pages/publications/84903616753#tab=citedBy

U2 - 10.1016/j.cplett.2014.06.027

DO - 10.1016/j.cplett.2014.06.027

M3 - Article

SN - 0009-2614

VL - 609

SP - 1

EP - 5

JO - Chemical Physics Letters

JF - Chemical Physics Letters

ER -

The permanent electric dipole moment of nickel oxide, NiO

Abstract

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