The permanent electric dipole moments of the X3Δ,E 3Π,A3Φ and B3Π states of titanium monoxide, TiO

Timothy Steimle; Wilton Virgo

doi:10.1016/j.cplett.2003.09.102

The permanent electric dipole moments of the X³Δ,E ³Π,A³Φ and B³Π states of titanium monoxide, TiO

Timothy Steimle
, Wilton Virgo

Molecular Sciences, School of (SMS)

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

The optical Stark spectrum of the origin bands of the E³Π₀-X³Δ₁,A³Φ ₂-X³Δ₁, and B³Π ₀-X³Δ₁ electronic transitions of titanium monoxide, TiO, were analyzed to produce permanent electric dipole moments of 3.34(1), 3.2(4), 4.89(5) and 4.9(2) D for the X³Δ₁,E³Π₀, A³Φ₂ and B³Π₀ states, respectively. The observations are compared with a simple molecular orbital description for the low-lying states and electronic structure calculations.

Original language	English (US)
Pages (from-to)	30-36
Number of pages	7
Journal	Chemical Physics Letters
Volume	381
Issue number	1-2
DOIs	https://doi.org/10.1016/j.cplett.2003.09.102
State	Published - Nov 4 2003

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1016/j.cplett.2003.09.102

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title = "The permanent electric dipole moments of the X3Δ,E 3Π,A3Φ and B3Π states of titanium monoxide, TiO",

abstract = "The optical Stark spectrum of the origin bands of the E3Π0-X3Δ1,A3Φ 2-X3Δ1, and B3Π 0-X3Δ1 electronic transitions of titanium monoxide, TiO, were analyzed to produce permanent electric dipole moments of 3.34(1), 3.2(4), 4.89(5) and 4.9(2) D for the X3Δ1,E3Π0, A3Φ2 and B3Π0 states, respectively. The observations are compared with a simple molecular orbital description for the low-lying states and electronic structure calculations.",

author = "Timothy Steimle and Wilton Virgo",

note = "Funding Information: This work was supported by a grant from the National Science Foundation {\textendash} Experimental Physical Chemistry (CHE-0078899).",

year = "2003",

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doi = "10.1016/j.cplett.2003.09.102",

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T1 - The permanent electric dipole moments of the X3Δ,E 3Π,A3Φ and B3Π states of titanium monoxide, TiO

AU - Steimle, Timothy

AU - Virgo, Wilton

N1 - Funding Information: This work was supported by a grant from the National Science Foundation – Experimental Physical Chemistry (CHE-0078899).

PY - 2003/11/4

Y1 - 2003/11/4

N2 - The optical Stark spectrum of the origin bands of the E3Π0-X3Δ1,A3Φ 2-X3Δ1, and B3Π 0-X3Δ1 electronic transitions of titanium monoxide, TiO, were analyzed to produce permanent electric dipole moments of 3.34(1), 3.2(4), 4.89(5) and 4.9(2) D for the X3Δ1,E3Π0, A3Φ2 and B3Π0 states, respectively. The observations are compared with a simple molecular orbital description for the low-lying states and electronic structure calculations.

AB - The optical Stark spectrum of the origin bands of the E3Π0-X3Δ1,A3Φ 2-X3Δ1, and B3Π 0-X3Δ1 electronic transitions of titanium monoxide, TiO, were analyzed to produce permanent electric dipole moments of 3.34(1), 3.2(4), 4.89(5) and 4.9(2) D for the X3Δ1,E3Π0, A3Φ2 and B3Π0 states, respectively. The observations are compared with a simple molecular orbital description for the low-lying states and electronic structure calculations.

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DO - 10.1016/j.cplett.2003.09.102

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JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1-2

ER -

The permanent electric dipole moments of the X³Δ,E ³Π,A³Φ and B³Π states of titanium monoxide, TiO

Abstract

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